A synthetic diamond (also known as a laboratory-grown diamond, a cultured diamond, or a cultivated diamond) is a diamond produced by a controlled process, as contrasted with a natural diamond created by geological processes or an imitation diamond made of non-diamond material that appears similar to a diamond. Synthetic diamond is also widely known as HPHT diamond or CVD diamond, after the two common production methods (referring to the high-pressure high-temperature and chemical vapor deposition crystal formation methods, respectively). While the term synthetic may sometimes be associated by consumers with imitation products, synthetic diamonds are made of the same material as natural diamonds—pure carbon, crystallized in an isotropic 3D form.
The properties of synthetic diamond depend on the details of the manufacturing processes; however, some synthetic diamonds (whether formed by HPHT or CVD) have properties such as hardness, thermal conductivity and electron mobility that are superior to those of most naturally formed diamonds. Synthetic diamond is widely used in abrasives, in cutting and polishing tools and in heat sinks. Electronic applications of synthetic diamond are being developed, including high-power switches at power stations, high-frequency field-effect transistors and light-emitting diodes. Synthetic diamond detectors of ultraviolet (UV) light or high-energy particles are used at high-energy research facilities and are available commercially. Because of its unique combination of thermal and chemical stability, low thermal expansion and high optical transparency in a wide spectral range, synthetic diamond is becoming the most popular material for optical windows in high-power CO2 lasers and gyrotrons. It is estimated that 98% of industrial grade diamond demand is supplied with synthetic diamonds.[2]
There are several methods used to produce synthetic diamonds. The original method uses high pressure and high temperature (HPHT) and is still widely used because of its relatively low cost. The process involves large presses that can weigh hundreds of tons to produce a pressure of 5 GPa at 1500 °C. The second method, using chemical vapor deposition (CVD), creates a carbon plasma over a substrate onto which the carbon atoms deposit to form diamond. Other methods include explosive formation (forming detonation nanodiamonds) and sonication of graphite solutions.
Chemical vapor deposition(C.V.D).is a method by which diamond can be grown from a hydrocarbon gas mixture. Since the early 1980s, this method has been the subject of intensive worldwide research. Whereas the mass-production of high-quality diamond crystals make the HPHT process the more suitable choice for industrial applications, the flexibility and simplicity of CVD setups explain the popularity of CVD growth in laboratory research. The advantages of CVD diamond growth include the ability to grow diamond over large areas and on various substrates, and the fine control over the chemical impurities and thus properties of the diamond produced. Unlike HPHT, CVD process does not require high pressures, as the growth typically occurs at pressures under 27 kPa.
The CVD growth involves substrate preparation, feeding varying amounts of gases into a chamber and energizing them. The substrate preparation includes choosing an appropriate material and its crystallographic orientation; cleaning it, often with a diamond powder to abrade a non-diamond substrate; and optimizing the substrate temperature (about800 °C) during the growth through a series of test runs. The gases always include a carbon source, typicallymethane, and hydrogen with a typical ratio of 1:99. Hydrogen is essential because it selectively etches off non-diamond carbon. The gases are ionized into chemically activeradicalsin the growth chamber usingmicrowavepower, ahot filament, anarc discharge, awelding torch, alaser, anelectron beam, or other means.
During the growth, the chamber materials are etched off by the plasma and can incorporate into the growing diamond. In particular, CVD diamond is often contaminated by silicon originating from thesilicawindows of the growth chamber or from the silicon substrate.[53]Therefore, silica windows are either avoided or moved away from the substrate. Boron-containing species in the chamber, even at very low trace levels, also make it unsuitable for the growth of pure diamond.
Hardness
Synthetic diamond is the hardest known material, where hardness is defined as resistance to indentation. The hardness of synthetic diamond depends on its purity, crystalline perfection and orientation: hardness is higher for flawless, pure crystals oriented to the direction (along the longest diagonal of the cubic diamond lattice).Nano crystalline diamond produced through C.V.D diamond growth can have a hardness ranging from 30% to 75% of that of single crystal diamond, and the hardness can be controlled for specific applications. Some synthetic single-crystal diamonds and H.P.H.T nano crystalline diamonds (see hyper diamond) are harder than any known natural diamond.
Ruby vs. pink sapphire :Generally, gemstone-quality corundum in all shades of red, including pink, are called rubies.[6][7] However, in the United States, a minimum color saturation must be met to be called a ruby; otherwise, the stone will be called a pink sapphire.Drawing a distinction between rubies and pink sapphires is relatively new, having arisen sometime in the 20th century. Often, the distinction between ruby and pink sapphire is not clear and can be debated.[8] As a result of the difficulty and subjectiveness of such distinctions, trade organizations such as the International Colored Gemstone Association (ICGA) have adopted the broader definition for ruby which encompasses its lighter shades, including pink.
Synthetic Diamond
The properties of synthetic diamond depend on the details of the manufacturing processes; however, some synthetic diamonds (whether formed by HPHT or CVD) have properties such as hardness, thermal conductivity and electron mobility that are superior to those of most naturally formed diamonds. Synthetic diamond is widely used in abrasives, in cutting and polishing tools and in heat sinks. Electronic applications of synthetic diamond are being developed, including high-power switches at power stations, high-frequency field-effect transistors and light-emitting diodes. Synthetic diamond detectors of ultraviolet (UV) light or high-energy particles are used at high-energy research facilities and are available commercially. Because of its unique combination of thermal and chemical stability, low thermal expansion and high optical transparency in a wide spectral range, synthetic diamond is becoming the most popular material for optical windows in high-power CO2 lasers and gyrotrons. It is estimated that 98% of industrial grade diamond demand is supplied with synthetic diamonds.[2]
Synthetic Diamond Manufacturing technologies.
There are several methods used to produce synthetic diamonds. The original method uses high pressure and high temperature (HPHT) and is still widely used because of its relatively low cost. The process involves large presses that can weigh hundreds of tons to produce a pressure of 5 GPa at 1500 °C. The second method, using chemical vapor deposition (CVD), creates a carbon plasma over a substrate onto which the carbon atoms deposit to form diamond. Other methods include explosive formation (forming detonation nanodiamonds) and sonication of graphite solutions.
Chemical vapor deposition(C.V.D). is a method by which diamond can be grown from a hydrocarbon gas mixture. Since the early 1980s, this method has been the subject of intensive worldwide research. Whereas the mass-production of high-quality diamond crystals make the HPHT process the more suitable choice for industrial applications, the flexibility and simplicity of CVD setups explain the popularity of CVD growth in laboratory research. The advantages of CVD diamond growth include the ability to grow diamond over large areas and on various substrates, and the fine control over the chemical impurities and thus properties of the diamond produced. Unlike HPHT, CVD process does not require high pressures, as the growth typically occurs at pressures under 27 kPa.
The CVD growth involves substrate preparation, feeding varying amounts of gases into a chamber and energizing them. The substrate preparation includes choosing an appropriate material and its crystallographic orientation; cleaning it, often with a diamond powder to abrade a non-diamond substrate; and optimizing the substrate temperature (about 800 °C) during the growth through a series of test runs. The gases always include a carbon source, typically methane, and hydrogen with a typical ratio of 1:99. Hydrogen is essential because it selectively etches off non-diamond carbon. The gases are ionized into chemically active radicals in the growth chamber using microwave power, a hot filament, an arc discharge, a welding torch, a laser, an electron beam, or other means.
During the growth, the chamber materials are etched off by the plasma and can incorporate into the growing diamond. In particular, CVD diamond is often contaminated by silicon originating from the silica windows of the growth chamber or from the silicon substrate.[53] Therefore, silica windows are either avoided or moved away from the substrate. Boron-containing species in the chamber, even at very low trace levels, also make it unsuitable for the growth of pure diamond.
Hardness
Synthetic diamond is the hardest known material, where hardness is defined as resistance to indentation. The hardness of synthetic diamond depends on its purity, crystalline perfection and orientation: hardness is higher for flawless, pure crystals oriented to the direction (along the longest diagonal of the cubic diamond lattice).Nano crystalline diamond produced through C.V.D diamond growth can have a hardness ranging from 30% to 75% of that of single crystal diamond, and the hardness can be controlled for specific applications. Some synthetic single-crystal diamonds and H.P.H.T nano crystalline diamonds (see hyper diamond) are harder than any known natural diamond.
Corundum
General.
(repeating unit)
2O
3
H-M symbol: (3 2/m)
Identification.
nε = 1.759–1.763
Ruby
Ruby.
(repeating unit)
H-M symbol: (3 2/m)
nε=1.760–1.763
Red under longwave
Ruby vs. pink sapphire :Generally, gemstone-quality corundum in all shades of red, including pink, are called rubies.[6][7] However, in the United States, a minimum color saturation must be met to be called a ruby; otherwise, the stone will be called a pink sapphire.Drawing a distinction between rubies and pink sapphires is relatively new, having arisen sometime in the 20th century. Often, the distinction between ruby and pink sapphire is not clear and can be debated.[8] As a result of the difficulty and subjectiveness of such distinctions, trade organizations such as the International Colored Gemstone Association (ICGA) have adopted the broader definition for ruby which encompasses its lighter shades, including pink.
Crystal structure of rubies.